Native Plants
of the Carolinas
Manual of the Vascular Flora of the Carolinas
Albert E. Radford, Harry E. Ahles, C. Ritchie Bell
Originally published in 1964, this is still the bible for many of us. If a plant was known to exist in the Carolinas, it's in this book, along with a detailed description, a map of its range, and perhaps a line drawing. (An invaluable reference — plan on keeping a bookmark tucked in the glossary of
botanical terms.)
The University of North Carolina Press.